Head to Head
| Champions League Women | 2019/11/02 16:00 | Maria Xiao v Sofia Polcanova | W | 2-3 |
| Champions League Women | 2019/09/15 15:00 | Sofia Polcanova v Maria Xiao | W | 3-0 |
Home History
| World Team Olympic Quals Women | 2020/01/22 15:00 | Hana Matelova v Sofia Polcanova | W | 1-3 |
| Champions League Women | 2020/01/10 20:30 | Pauline Chasselin v Sofia Polcanova | W | 0-3 |
| Champions League Women | 2020/01/10 19:10 | Adina Diaconu v Sofia Polcanova | W | 1-3 |
| Champions League Women | 2019/12/01 17:00 | Sofia Polcanova v Wing Nam Ng | L | 2-3 |
| Champions League Women | 2019/12/01 15:00 | Sofia Polcanova v Natalia Partyka | W | 3-0 |
| Austria Top 12 Women | 2019/11/25 19:15 | Sofia Polcanova v Jia Liu | W | 3-1 |
| Austria Top 12 Women | 2019/11/25 17:20 | Sofia Polcanova v Karoline Mischek | W | 3-1 |
| Austria Top 12 Women | 2019/11/25 14:40 | Sofia Polcanova v Ines Diendorfer | W | 3-0 |
Away History
| World Team Olympic Quals Women | 2020/01/22 15:00 | Tin-Tin Ho v Maria Xiao | W | 0-3 |
| European Champions League Women | 2019/12/06 19:00 | Wing Nam Ng v Maria Xiao | L | 3-2 |
| European Champions League Women | 2019/12/06 17:40 | Natalia Partyka v Maria Xiao | W | 1-3 |
| Champions League Women | 2019/11/02 16:00 | Maria Xiao v Sofia Polcanova | L | 2-3 |
| Champions League Women | 2019/10/25 17:10 | Maria Xiao v Wing Nam Ng | L | 0-3 |
| Champions League Women | 2019/09/15 15:00 | Sofia Polcanova v Maria Xiao | L | 3-0 |
| Champions League Women | 2019/09/15 13:40 | Yui Hamamoto v Maria Xiao | L | 3-0 |
| Euro Team Champs Women | 2019/09/05 14:30 | Elizabeta Samara v Maria Xiao | L | 3-2 |
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