[4] Shakhtar Donetsk 0-5 Real Madrid [2] 2021-10-19 19:00
Stadium: Olimpiyskiy National Sports Complex Round: 3
Referee: Srdjan Jovanovic Home Manager: Roberto De Zerbi Away Manager: Carlo Ancelotti
Head to Head
| UEFA Champions League | 2020/12/01 17:55 | Shakhtar Donetsk v Real Madrid | W | 2-0 |
| UEFA Champions League | 2020/10/21 16:55 | Real Madrid v Shakhtar Donetsk | W | 2-3 |
| UEFA Champions League | 2015/11/25 19:45 | Shakhtar Donetsk v Real Madrid | L | 3-4 |
| UEFA Champions League | 2015/09/15 18:45 | Real Madrid v Shakhtar Donetsk | L | 4-0 |
Home History
| Ukraine Vyscha Liga | 2021/10/15 14:00 | Shakhtar Donetsk v FC Zorya Lugansk | W | 6-1 |
| Ukraine Vyscha Liga | 2021/10/03 16:30 | Dynamo Kiev v Shakhtar Donetsk | D | 0-0 |
| UEFA Champions League | 2021/09/28 16:45 | Shakhtar Donetsk v Inter Milan | D | 0-0 |
| Ukraine Vyscha Liga | 2021/09/25 14:00 | Shakhtar Donetsk v FC Veres Rivne | W | 4-1 |
| Ukraine Supercup | 2021/09/22 18:00 | Shakhtar Donetsk v Dynamo Kiev | W | 3-0 |
| Ukraine Vyscha Liga | 2021/09/18 14:00 | FC Mariupol v Shakhtar Donetsk | W | 0-5 |
| UEFA Champions League | 2021/09/15 16:45 | Sheriff Tiraspol v Shakhtar Donetsk | L | 2-0 |
| Ukraine Vyscha Liga | 2021/09/11 16:30 | Shakhtar Donetsk v Dnipro-1 | W | 2-0 |
Away History
| Spain Primera Liga | 2021/10/03 14:15 | Espanyol v Real Madrid | L | 2-1 |
| UEFA Champions League | 2021/09/28 19:00 | Real Madrid v Sheriff Tiraspol | L | 1-2 |
| Spain Primera Liga | 2021/09/25 19:00 | Real Madrid v Villarreal | D | 0-0 |
| Spain Primera Liga | 2021/09/22 20:00 | Real Madrid v Mallorca | W | 6-1 |
| Spain Primera Liga | 2021/09/19 19:00 | Valencia v Real Madrid | W | 1-2 |
| UEFA Champions League | 2021/09/15 19:00 | Inter Milan v Real Madrid | W | 0-1 |
| Spain Primera Liga | 2021/09/12 19:00 | Real Madrid v Celta Vigo | W | 5-2 |
| Spain Primera Liga | 2021/08/28 20:00 | Real Betis v Real Madrid | W | 0-1 |
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