| World Championship Women | 2021/11/23 19:00 | Adriana Diaz v Aikaterini Toliou | L | 4-0 |
| European Team Championships Women | 2021/09/29 10:40 | Polina Mikhaylova v Aikaterini Toliou | L | 3-1 |
| European Team Championships Women | 2021/09/28 07:05 | Xia Lian Ni v Aikaterini Toliou | L | 3-0 |
| Europe Top 16 Cup Women | 2021/09/18 11:00 | Georgina Pota v Aikaterini Toliou | L | 4-2 |
| Euro Champs Team Women Quals | 2021/08/28 13:00 | Sibel Altinkaya v Aikaterini Toliou | L | 3-2 |
| Euro Champs Team Women Quals | 2021/08/28 11:00 | Ece Harac v Aikaterini Toliou | W | 1-3 |
| Euro Champs Team Women Quals | 2021/08/27 08:00 | Aikaterini Toliou v Dzana Biogradlic | W | 3-1 |
| Czech Open Women | 2021/08/24 10:10 | Xiaoxin Yang v Aikaterini Toliou | L | 4-0 |
| WTT Feeder Dusseldorf Women | 2022/01/18 11:15 | Gaia Monfardini v Jeanne Robbes | W | 4-2 |
| WTT Contender Novo Mesto Women | 2021/11/09 15:45 | Gaia Monfardini v Weishan Liu | L | 0-3 |
| WTT Contender Novo Mesto Women | 2021/11/08 13:15 | Gaia Monfardini v Rui Xuan Goi | W | 3-2 |
| European Championships Women | 2021/06/23 08:45 | Katsiaryna Baravok v Gaia Monfardini | L | 3-0 |
| European Championships Women | 2021/06/22 10:10 | Filippa Bergand v Gaia Monfardini | L | 3-0 |
| Balkan Champs WS | 2019/08/03 10:30 | Ivana Vejnovic v Gaia Monfardini | W | 1-4 |
| Balkan Champs Team Women | 2019/07/31 12:00 | Gul Pembe Ozkaya v Gaia Monfardini | W | 2-3 |