| WTA Moscow | 10/18 11:30 | 25 | [23] Anastasia Pavlyuchenkova v Katerina Siniakova [52] | 7-6,5-7,7-5 | |
| WTA Linz | 10/14 15:30 | 27 | [21] Anastasia Pavlyuchenkova v Dominika Cibulkova [10] | 6-7,4-6 | |
| WTA Linz | 10/13 13:00 | 26 | [21] Anastasia Pavlyuchenkova v Kirsten Flipkens [59] | 6-4,7-6 | |
| WTA Linz | 10/10 16:30 | 25 | [21] Anastasia Pavlyuchenkova v Anastasija Sevastova [31] | 6-4,6-1 | |
| WTA Beijing | 10/02 10:20 | 24 | [17] Anastasia Pavlyuchenkova v Alison Riske [57] | 6-7,1-6 | |
| WTA Wuhan | 09/26 04:00 | 24 | Anastasia Pavlyuchenkova v Misaki Doi | Retired | |
| WTA Tokyo | 09/22 11:20 | 26 | Elina Svitolina v Anastasia Pavlyuchenkova | 7-6,6-4 | |
| WTA Tokyo | 09/20 08:20 | 25 | Andrea Petkovic v Anastasia Pavlyuchenkova | Retired | |
| US Open 2016 Women | 09/03 20:15 | 25 | Karolina Pliskova v Anastasia Pavlyuchenkova | 6-2,6-4 | |
| US Open 2016 Women | 09/01 16:20 | 24 | Kristina Mladenovic v Anastasia Pavlyuchenkova | 2-6,6-4,6-7 | |
| US Open 2016 Women | 08/30 20:10 | 23 | Louisa Chirico v Anastasia Pavlyuchenkova | 1-6,4-6 | |
| WTA Montreal | 07/29 22:30 | 27 | Anastasia Pavlyuchenkova v Madison Keys | 6-7,6-1,0-6 | |
| WTA Montreal | 07/28 18:30 | 26 | Agnieszka Radwanska v Anastasia Pavlyuchenkova | 4-6,7-6,1-6 | |
| WTA Montreal | 07/27 16:30 | 25 | Christina McHale v Anastasia Pavlyuchenkova | 2-6,5-7 | |
| WTA Montreal | 07/26 16:30 | 24 | Yulia Putintseva v Anastasia Pavlyuchenkova | 4-6,6-1,5-7 | |
| Wimbledon Women | 07/05 13:55 | 27 | Serena Williams v Anastasia Pavlyuchenkova | 6-4,6-4 | |
| Wimbledon Women | 07/04 10:30 | 26 | Anastasia Pavlyuchenkova v Coco Vandeweghe | 6-3,6-3 | |
| Wimbledon Women | 07/03 10:30 | 25 | Timea Bacsinszky v Anastasia Pavlyuchenkova | 3-6,2-6 | |
| Wimbledon Women | 07/01 13:15 | 24 | Yulia Putintseva v Anastasia Pavlyuchenkova | 5-7,1-6 | |
| Wimbledon Women | 06/28 14:05 | 23 | Su-Wei Hsieh v Anastasia Pavlyuchenkova | 5-7,6-1,1-6 | |
| Billie Jean King Cup | 11/15 13:55 | 1 | Karolina Pliskova v Anastasia Pavlyuchenkova | 6-3,6-4 | |
| Billie Jean King Cup | 11/14 13:00 | 1 | Petra Kvitova v Anastasia Pavlyuchenkova | 2-6,6-1,6-1 | |
| Wimbledon Women | 07/02 10:30 | 24 | Anastasia Pavlyuchenkova v Angelique Kerber | 5-7,2-6 | |
| Wimbledon Women | 06/30 10:30 | 23 | Anastasia Pavlyuchenkova v Mona Barthel | 6-7,7-6,6-2 | |
| Billie Jean King Cup | 04/18 13:05 | 1 | Anastasia Pavlyuchenkova v Sabine Lisicki | 4-6,7-6,6-3 | |
| WTA Montreal | 08/05 16:00 | 24 | Anastasia Pavlyuchenkova v Venus Williams | 1-6,6-3,2-6 | |
| Wimbledon Women | 06/24 17:40 | 23 | Anastasia Pavlyuchenkova v Alison Riske-Amritraj | 6-4,5-7,1-6 |