| WTA Tokyo | 09/19 04:40 | 26 | [28] Anastasia Pavlyuchenkova v Caroline Garcia [4] | 4-6,6-2,5-7 | |
| WTA Tokyo | 09/17 10:50 | 25 | [28] Anastasia Pavlyuchenkova v Aliaksandra Sasnovich [31] | 6-3,6-4 | |
| US Open Women | 08/27 17:10 | 23 | [61] Rebecca Peterson v Anastasia Pavlyuchenkova [28] | 1-6,6-4,6-3 | |
| WTA Cincinnati | 08/15 19:00 | 25 | [4] Angelique Kerber v Anastasia Pavlyuchenkova [28] | 4-6,7-5,6-4 | |
| WTA Cincinnati | 08/14 18:20 | 24 | [28] Anastasia Pavlyuchenkova v Aleksandra Krunic [47] | 6-1,6-0 | |
| WTA Montreal | 08/08 22:30 | 25 | [1] Simona Halep v Anastasia Pavlyuchenkova [28] | 7-6,4-6,7-5 | |
| WTA Montreal | 08/07 21:35 | 24 | [28] Anastasia Pavlyuchenkova v Christina McHale [98] | 6-3,6-2 | |
| Wimbledon Women | 07/03 10:30 | 23 | [48] Su-Wei Hsieh v Anastasia Pavlyuchenkova [29] | 6-4,4-6,6-3 | |
| WTA Eastbourne | 06/25 12:45 | 25 | [29] Anastasia Pavlyuchenkova v Karolina Pliskova [7] | 4-6,6-2,3-6 | |
| WTA Eastbourne | 06/24 10:00 | 24 | [28] Anastasia Pavlyuchenkova v Sorana Cirstea [49] | 2-6,7-5,6-4 | |
| WTA Birmingham | 06/19 16:20 | 25 | [3] Garbine Muguruza v Anastasia Pavlyuchenkova [28] | 6-1,6-2 | |
| French Open Women | 05/31 09:00 | 24 | [90] Samantha Stosur v Anastasia Pavlyuchenkova [28] | 6-2,7-6 | |
| French Open Women | 05/29 14:00 | 23 | [58] Polona Hercog v Anastasia Pavlyuchenkova [28] | 4-6,6-7 | |
| WTA Strasbourg | 05/26 13:00 | 29 | [31] Anastasia Pavlyuchenkova v Dominika Cibulkova [36] | 6-7,7-6,7-6 | |
| WTA Strasbourg | 05/25 14:30 | 28 | [17] Ashleigh Barty v Anastasia Pavlyuchenkova [31] | Retired | |
| WTA Strasbourg | 05/24 10:45 | 27 | [31] Anastasia Pavlyuchenkova v Zarina Diyas [53] | 6-4,6-2 | |
| WTA Strasbourg | 05/23 09:00 | 26 | Anastasia Pavlyuchenkova v Natalia Vikhlyantseva | 6-4,6-4 | |
| WTA Strasbourg | 05/21 16:40 | 25 | [31] Anastasia Pavlyuchenkova v Tatjana Maria [64] | 6-0,6-0 | |
| WTA Rome | 05/14 12:20 | 24 | [29] Anastasia Pavlyuchenkova v Madison Keys [14] | 4-6,1-6 | |
| WTA Madrid | 05/06 09:00 | 24 | [57] Samantha Stosur v Anastasia Pavlyuchenkova [27] | 6-1,6-7,6-3 | |
| WTA Stuttgart | 04/27 16:30 | 27 | [31] Anett Kontaveit v Anastasia Pavlyuchenkova [27] | 7-5,6-7,6-4 | |
| WTA Stuttgart | 04/26 17:45 | 26 | [27] Anastasia Pavlyuchenkova v Garbine Muguruza [3] | Retired | |
| WTA Stuttgart | 04/25 09:30 | 25 | [13] Madison Keys v Anastasia Pavlyuchenkova [27] | 6-7,7-5,4-6 | |
| 2018 Fed Cup | 04/22 08:10 | 27 | [27] Anastasia Pavlyuchenkova v Jelena Ostapenko [5] | 5-7,1-6 | |
| 2018 Fed Cup | 04/21 09:10 | 27 | [27] Anastasia Pavlyuchenkova v Anastasija Sevastova [15] | 6-3,2-6,6-4 | |
| WTA Miami | 03/24 22:15 | 25 | [10] Angelique Kerber v Anastasia Pavlyuchenkova [25] | 6-4,6-4 | |
| WTA Miami | 03/22 17:05 | 24 | [46] Aliaksandra Sasnovich v Anastasia Pavlyuchenkova [25] | 2-6,6-3,2-6 | |
| WTA Indian Wells | 03/10 03:30 | 24 | Amanda Anisimova v Anastasia Pavlyuchenkova | 6-4,6-1 | |
| WTA Dubai | 02/19 16:30 | 25 | Johanna Konta v Anastasia Pavlyuchenkova | 7-6,6-2 | |
| WTA Doha | 02/12 09:00 | 24 | Dominika Cibulkova v Anastasia Pavlyuchenkova | 7-6,6-4 |