| WTA Monterrey | 04/04 01:00 | 26 | [33] Anastasia Pavlyuchenkova v Ivana Jorovic [100] | 6-0,6-0 | |
| WTA Monterrey | 04/02 20:00 | 25 | [33] Anastasia Pavlyuchenkova v Anna Blinkova [117] | 6-0,6-3 | |
| WTA Miami | 03/22 17:20 | 24 | [33] Anastasia Pavlyuchenkova v Viktoria Kuzmova [48] | 7-6,4-6,5-7 | |
| WTA Indian Wells | 03/09 23:00 | 24 | [140] Christina McHale v Anastasia Pavlyuchenkova [32] | 6-4,3-6,6-4 | |
| WTA Dubai | 02/18 18:20 | 24 | [20] Caroline Garcia v Anastasia Pavlyuchenkova [32] | 6-2,6-0 | |
| 2019 Fed Cup | 02/09 17:55 | 29 | [32] Anastasia Pavlyuchenkova v Rebecca Peterson [54] | 6-3,6-2 | |
| 2019 Fed Cup | 02/06 16:15 | 1 | [32] Anastasia Pavlyuchenkova v Magda Linette [89] | 6-4,6-3 | |
| WTA St. Petersburg | 02/01 13:30 | 27 | [32] Anastasia Pavlyuchenkova v Kiki Bertens [8] | 2-6,6-3,0-6 | |
| WTA St. Petersburg | 01/31 13:15 | 26 | [22] Jelena Ostapenko v Anastasia Pavlyuchenkova [32] | 4-6,4-6 | |
| WTA St. Petersburg | 01/29 15:50 | 25 | [50] Alize Cornet v Anastasia Pavlyuchenkova [32] | 5-7,6-7 | |
| Australian Open Women | 01/22 05:10 | 27 | [44] Anastasia Pavlyuchenkova v Danielle Collins [35] | 6-2,5-7,1-6 | |
| Australian Open Women | 01/20 12:10 | 26 | [5] Sloane Stephens v Anastasia Pavlyuchenkova [44] | 7-6,3-6,3-6 | |
| Australian Open Women | 01/18 03:25 | 25 | [31] Aliaksandra Sasnovich v Anastasia Pavlyuchenkova [44] | 0-6,3-6 | |
| Australian Open Women | 01/16 00:00 | 24 | [44] Anastasia Pavlyuchenkova v Kiki Bertens [9] | 3-6,6-3,6-3 | |
| Australian Open Women | 01/14 03:00 | 23 | [54] Monica Puig v Anastasia Pavlyuchenkova [44] | 4-6,3-6 | |
| WTA Hobart | 01/07 05:00 | 25 | [42] Anastasia Pavlyuchenkova v Vera Lapko [65] | 3-6,6-3,3-6 | |
| WTA Shenzhen | 01/01 09:50 | 26 | [42] Anastasia Pavlyuchenkova v Veronika Kudermetova [134] | 2-6,6-1,2-6 | |
| WTA Shenzhen | 12/30 04:00 | 25 | [42] Anastasia Pavlyuchenkova v Ana Bogdan [76] | 6-0,6-1 | |
| WTA Moscow | 10/18 15:30 | 27 | [40] Anastasia Pavlyuchenkova v Daria Kasatkina [14] | 4-6,3-6 | |
| WTA Moscow | 10/17 10:45 | 26 | [170] Valentini Grammatikopoulou v Anastasia Pavlyuchenkova [40] | 5-7,0-6 | |
| WTA Moscow | 10/17 07:00 | - | Simona Halep v Anastasia Pavlyuchenkova | Cancelled | |
| WTA Moscow | 10/15 11:20 | 25 | [40] Anastasia Pavlyuchenkova v Ajla Tomljanovic [46] | 7-5,6-4 | |
| WTA Linz | 10/12 18:25 | 27 | [119] Ekaterina Alexandrova v Anastasia Pavlyuchenkova [35] | 6-3,7-5 | |
| WTA Linz | 10/10 12:55 | 26 | [62] Vera Lapko v Anastasia Pavlyuchenkova [35] | 7-5,6-7,3-6 | |
| WTA Linz | 10/08 13:00 | 25 | [57] Viktoria Kuzmova v Anastasia Pavlyuchenkova [35] | 5-7,5-7 | |
| WTA Beijing | 09/30 11:30 | 24 | [9] Sloane Stephens v Anastasia Pavlyuchenkova [39] | 6-7,6-4,6-4 | |
| WTA Wuhan | 09/27 06:30 | 27 | [17] Ashleigh Barty v Anastasia Pavlyuchenkova [39] | 6-2,5-7,6-4 | |
| WTA Wuhan | 09/26 04:40 | 26 | [39] Anastasia Pavlyuchenkova v Petra Kvitova [5] | 3-6,6-3,6-3 | |
| WTA Wuhan | 09/25 07:50 | 25 | [11] Kiki Bertens v Anastasia Pavlyuchenkova [39] | 4-6,2-6 | |
| WTA Wuhan | 09/23 08:00 | 24 | [28] Anastasia Pavlyuchenkova v Anastasija Sevastova [19] | 6-2,6-3 |